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                ProductsYour location:Products

                Nickel Nitrate

                MSDS Number: KWC-011
                Effective Date:NOV.16,2004

                1. Product Identification
                Synonyms : Nickel (II) nitrate, hexahydrate (1:2:6); nickelous nitrate; nitric acid, nickel (2+) salt, hexahydrate; Nickelous nitrate, 6- Hydrate
                CAS No. : 13138-45-9 Anhydrous; 13478-00-7 Hexahydrate
                Molecular Weight : 290.83
                Chemical Formula :Ni(NO3)2 . 6H2O

                2. Composition/Information on Ingredients

                Ingredient

                CAS No

                Percent

                Hazardous

                Nickel Nitrate

                13138-45-9

                98%

                Yes

                3. Hazards Identification
                Emergency Overview
                DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
                HeBei KingWay Chemical Industry Co., Ltd (Provided here for your convenience)

                Health Rating:
                3 - Severe (Cancer Causing)
                Flammability Rating:
                0 - None
                Reactivity Rating:
                3 - Severe (Oxidizer)
                Contact Rating:
                3 - Severe (Life)
                Lab Protective Equip:
                GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
                Storage Color Code:
                Yellow (Reactive)

                Potential Health Effects
                Inhalation:
                Causes irritation to the respiratory tract. Symptoms may include coughing, sore throat, and shortness of breath. Lung damage may result from a single high exposure or lower repeated exposures. Lung allergy occasionally occurs, with asthma type symptoms.
                Ingestion:
                Toxic. Symptoms may include abdominal pain, diarrhea, nausea, and vomiting. Absorption is poor, but should it occur, symptoms may include giddiness, capillary damage, myocardial weakness, central nervous system depression, and kidney and liver damage.
                Skin Contact:
                Causes irritation. May cause skin allergy with itching, redness or rash. Some individuals may become sensitized to the substance and suffer "nickel itch", a form of dermatitis.
                Eye Contact:
                Causes irritation, redness, and pain.
                Chronic Exposure:
                Prolonged or repeated exposure to excessive concentrations may affect lungs, liver and kidneys. Chronic exposure to nickel and nickel compounds is associated with cancer.
                Aggravation of Pre-existing Conditions:
                Persons with pre-existing skin disorders, impaired respiratory or pulmonary function, or with a history of asthma, allergies, or sensitization to nickel compounds may be at an increased risk upon exposure to this substance.

                4. First Aid Measures
                Inhalation:
                Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
                Ingestion:
                Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
                Skin Contact:
                Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
                Eye Contact:
                Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

                5. Fire Fighting Measures
                Fire:
                Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Increases the flammability of any combustible material.
                Explosion:
                Contact with oxidizable substances may cause extremely violent combustion. Strong oxidants may explode when shocked, or if exposed to heat, flame, or friction. Also may act as initiation source for dust or vapor explosions.
                Fire Extinguishing Media:
                Water or water spray in early stages of fire. Foam or dry chemical may also be used.
                Special Information:
                Wear full protective clothing and breathing equipment for high-intensity fire or potential explosion conditions.

                6. Accidental Release Measures
                Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container.

                7. Handling and Storage
                Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Areas in which exposure to nickel metal or soluble nickel compounds may occur should be identified by signs or appropriate means, and access to the area should be limited to authorized persons. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

                8. Exposure Controls/Personal Protection
                Airborne Exposure Limits:
                OSHA Permissible Exposure Limit (PEL): soluble Nickel compounds as Ni: 1 mg/m3 (TWA) ACGIH Threshold Limit Value (TLV): soluble Nickel compounds as Ni: 0.1 mg/m3 (TWA)
                Ventilation System:
                A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
                Personal Respirators (NIOSH Approved):
                If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
                Skin Protection:
                Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure.
                Eye Protection:
                Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
                Other Control Measures:
                Eating, drinking, and smoking should not be permitted in areas where solids or liquids containing soluble nickel compounds are handled, processed, or stored. NIOSH recommends pre-placement and periodic medical exams, with maintaining of records for all employees exposed to nickel in the workplace.

                9. Physical and Chemical Properties

                Appearance :
                Green, transparent crystals
                Odor :
                Odorless
                Solubility :
                238.5g/100cc water @ 0C
                Specific Gravity:
                2.05
                PH :
                3.5 - 5.5 (5% solution @ 25C (77F)
                % Volatiles by volume @ 21C (70F) :
                0
                Boiling Point :
                137C (279F)
                Melting Point :
                56.7C (135F)
                Vapor Density (Air=1) :
                No information found
                Vapor Pressure (mm Hg) :
                0 @ 20C (68F)
                Evaporation Rate (BuAc=1) :
                No information found

                10. Stability and Reactivity
                Stability:
                Stable under ordinary conditions of use and storage. Substance has both oxidant and reducing characteristics, and is unstable when heated or shocked.
                Hazardous Decomposition Products:
                Emits toxic fumes of nickel and nitrogen oxides when heated to decomposition.
                Hazardous Polymerization:
                Will not occur.
                Incompatibilities:
                Aluminum, boron phosphide, cyanides, esters, combustible material, phospham, phosphorus, sodium hypophosphite, stannous chloride, thiocyanates, strong reducing agents, and organic materials.
                Conditions to Avoid:
                Heat, shock, friction, incompatibles.

                11. Toxicological Information
                Nickelous Nitrate Hexahydrate; Oral rat LD50: 1620 mg/kg. Investigated as a tumorigen.
                Cancer Lists

                ---NTP Carcinogen---

                Ingredient
                Known
                Anticipated
                IARC Category
                Nickel Nitrate (13138-45-9)
                No
                Yes
                1

                12. Ecological Information
                Environmental Fate:
                When released into water, this material is not expected to evaporate significantly. This material is not expected to significantly bioaccumulate.
                Environmental Toxicity : No information found.

                13. Disposal Considerations
                Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

                14. Transport Information
                Domestic (Land, D.O.T.)
                Proper Shipping Name : RQ, NICKEL NITRATE
                Hazard Class : 5.1
                UN/NA : UN2725
                Packing Group : III
                Information reported for product/size : 300LB
                International (Water, I.M.O.)
                Proper Shipping Name : NICKEL NITRATE
                Hazard Class : 5.1
                UN/NA : UN2725
                Packing Group : III
                Information reported for product/size : 300LB

                15. Regulatory Information
                Chemical Inventory Status - Part 1

                Ingredient
                TSCA
                EC
                Japan
                Australia
                Nickel Nitrate (13138-45-9)
                Yes
                Yes
                Yes
                Yes

                Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
                SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
                Reactivity: Yes (Mixture / Solid)
                Prop 65:
                THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
                Australian Hazchem Code : 1Y
                Poison Schedule : No information found.
                WHMIS:
                This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

                16. Other Information
                NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Other: Oxidizer
                Label Hazard Warning:
                DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND
                RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
                Label Precautions:
                Do not store near combustible materials. Do not get in eyes, on skin, or on clothing. Remove and wash contaminated clothing promptly. Wash thoroughly after handling. Do not breathe dust. Keep container closed. Use only with adequate ventilation.
                Label First Aid:
                If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention.

                Disclaimer:
                Hebei Kingway Chemical Industry Co., Ltd provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product.Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. HeBei Kingway Chemical Industry Co., Ltd. makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. accordingly, HeBei Kingway Chemical Industry Co., Ltd. will not be responsible for damages resulting from use of or reliance upon this information.


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