Nickel Salts Series
Cadmium Salts Series
Inorganic Fluoride Salts Series
Fluoborate Salts Series
Fluosilicate Salts Series
Fluozirconate& Fluotitanate Salts Series
Strontium & lithium Salts Series
Photocatalyst Suspension
Other Series
| Nickel Fluoride |
|
Ingredient
|
CAS No
|
Percent
|
SARA 313
|
|
NICKEL(II) FLUORIDE TETRAHYDRATE
|
13940-83-5
|
Ni34.2%min
|
NO
|
3 - Hazards Identification
EMERGENCY OVERVIEW
Toxic.
May cause cancer. Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by inhalation and skin contact. Irritating to eyes, respiratory system and skin.
Target organ(s): Lungs.
For additional information on toxicity, please refer to Section 11.
4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
EYE EXPOSURE
Assure adequate flushing of the eyes by separating the eyelids with fingers.
5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
EXPOSURE HAZARD(S)
Material: Irritant. Sensitizer.
6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. Wear disposable coveralls and discard them after use.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed. Store in a cool dry place.
SPECIAL REQUIREMENTS
Hygroscopic.
8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
PERSONAL PROTECTIVE EQUIPMENT
Other: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before reuse.
9 - Physical/Chemical Properties
Appearance N/A
Property Value At Temperature or Pressure
Molecular Weight 168.77 AMU
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
10 - Stability and Reactivity
STABILITY
Conditions of Instability : Protect from moisture.
Conditions to Avoid : Protect from moisture.
Materials to Avoid : Peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products : Hydrogen fluoride.
11 - Toxicological Information
ROUTE OF EXPOSURE
Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation.
SENSITIZATION
Skin: May cause allergic skin reaction.
TARGET ORGAN(S) OR SYSTEM(S)
Lungs.
SIGNS AND SYMPTOMS OF EXPOSURE
Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. Dermatitis. Exposure can cause:Gastrointestinal disturbances.
CHRONIC EXPOSURE - CARCINOGEN
Result: Carcinogen.
12 - Ecological Information
13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
The material should be dissolved in: 1) water, 2) acid solution, or 3) oxidized to a water-soluble state. Precipitate the material as the sulfide, adjusting the pH of the solution to 7 to complete precipitation. Filter the insolubles and dispose of them in a hazardous waste site. Destroy any excess sulfide with sodium hypochlorite. Neutralize the solution before flushing down the drain. Observe all federal, state, and local environmental regulations.
14 - Transport Information
IATA
Proper Shipping Name : Toxic solid, inorganic, n.o.s.
IATA UN Number : 3288
Hazard Class : 6.1
Packing Group : III
15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: T
Indication of Danger: Toxic.
R: 25 40 43
Risk Statements: Toxic if swallowed. Limited evidence of a
carcinogenic effect. May cause sensitization by skin contact.
S: 22 36/37/39 45
Safety Statements: Do not breathe dust. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Toxic.
Risk Statements: May cause cancer. Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by inhalation and skin contact. Irritating to eyes, respiratory
system and skin.
Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection.
US Statements: Target organ(s): Lungs.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
NOTES: This product is subject to SARA section 313 reporting requirements. This product is subject to SARA section 313 reporting requirements.
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR.
DSL: No
NDSL: No
16 - Other Information
Disclaimer:
Hebei Kingway Chemical Industry Co., Ltd provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product.Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. HeBei Kingway Chemical Industry Co., Ltd. makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. accordingly, HeBei Kingway Chemical Industry Co., Ltd. will not be responsible for damages resulting from use of or reliance upon this information.